Yes. The resistance of a fully charged battery is measured in milliOhms and a difference of 0.5v with 1 mill ohm will allow a current of 500 amp!. .. now it does not get that large, only because the resistance of the wire and contacts needs to be added.
If you want to make a mega battery ...discharge both battery packs normally and place a resistance, .. a lamp bulb from a cheap 1.5v torch will do and eventually the batteries will equalise... The bulb might glow dull red for as while, but will eventually go of. Remove the lamp and replace with a wire link and charge normally. If there is a minute difference between the BMS on both batteries, the lower one will determine the maximum voltage attained by the combination..