Very bad photos again. Did you look at them before posting or are you joking with us?
Either way, it looks like pin 5, but you're photo is so bad, it might be pin 6. See if the broken pin is still in there. It might be easier to reattach that pin to the pcb rather than the connector.
The white stuff is silicone rubber, which doesn't cause cancer. I disassembled one of those batteries about 5 years ago, and I handled it a lot while I chipped it all away. I'm still here. I took photos of the inside and put them in Photo bucket, but I they wiped them out when I wouldn't pay.