It's great that people share their experience, but there's missing and misleading information in that video that could get someone in serious trouble if they tried it without knowing what they're doing.
The minimum cell-voltage that he mentions is much too low. 3.5v would be more like it, at which point the lipos should be disconnected to avoid running into the danger zone. You need real-time monitoring of the lipo voltage, not some meter burried in a bag. He doesn't mention that the controller's lvc has been eliminated and what that means for the main pack and how the size of the lipo pack affects that.
Finally, it's not really a speed hack. It's a power hack. The top speed is limited by the controlller. You'll note that he doesn't go over 25 kph. Obviously, with more power, it goes faster uphill.
It would be better if he made a link to some information that explained the principles of booster batteries, what's the upside and the risks.