There most certainly is - two important differences, in fact....
(1) The 230 volt ones are not usually designed to deal with huge surges (compared to their trip rating) as the circuits they find themselves in are properly fused further up the line. 12 volt ones expect to find themselves on batteries which might possibly deliver 800 or more amps into a short with no other protection between your breaker and the battery.
(2) Actually this is probably more important than the above: your 12 volt ones are expected to deal with DC supplies while your mains ones deal with AC supplies. Not wishing to overcomplicate things, breaking an AC circuit requires a relatively small gap between contacts, whereas breaking a DC circuit needs a substantial gap, good insulation, and the ability to withstand a flaming arc until the contacts have opened sufficiently.
So - your 12 volt breaker is a much more substantial item than might be needed for 230V, despite the fact that you might think the additional voltage would be the most important thing - it's not: it's the large DC fault currents and the inductance of the circuit which can make an arc persist long enough to do quite a bit of damage.
Rog.