Surely with your assembly method and using the charger you mentioned you have to unplug from power feed (1), remove blocks from your container, break the parallel connections first (2), .
I rarely use parallel connections.
I don't remove the blocks from the container. The container just lifts out of the pannier, with the batteries still inside.
break the serial connections (4), remove the monitor boards (4), charge each block separately, or use a parallel board, pushing it with a 40W charger, reassemble back into serial blocks (4), refit monitoring boards (4),
.
I use a parallel board. Plus, I have four chargers. I don't refit the monitoring boards, I do that when I connect the battery to the bike.
double check serial block voltage for any voltage difference between serial blocks before connecting back in parallel (2), refit back into container then reconnect power feed (1).
I am sure you are fully capable of working with lipos and of the safety required, but from many of the posts on this site there are many who do not and for that reason I do not usually contribute to these threads.
Arbol raised a suggestion of fusing each parallel branch something I would highly recommend.
I rarely use parallel connections.
I have my batteries (20C 4S 5AH hobbyking hardcase) taped together in pairs. Today, I put three pair in my pannier box, connected one pair to the bike (plug in two EC5s to driver cable, plug in two balance leads to monitors.
When the monitor starts to beep (or maybe before) I unplug the two EC5s and the balance leads, then plug into the next pair of batteries. It takes about a minute to do all that.
When I got home, I put the box with the batteries near my balance chargers, and plugged one charger into each battery pair (parallel charging the two 4ses).
I get extemely poor milage from my bike, because of how I'm riding. Today, I got about 9km from 160 watt-hours (5AH, 8s). That's because I'm not riding fast over tarmac, I'm riding fairly slowly over grass and mud, and stopping every few hundred meters. That's because I'm geocaching.
Because I get such poor mileage (and because I can't accurately predict how much milage I'll get from a battery because I can't predict the track conditions), it's good for me to be able to carry extra batteries. And because I occasionally need to lift over an obstacle, It's good that I can very quickly unplug the battery and remove the panniers, thereby lightening the bike for lifting.
I agree, what I do might be too complicated for some people. But I love the flexibility it gives me (I can carry anything from one pair giving me 8s 5AH up to seven pair if I'm going a very long way).