You can buy the cheapest wattmeter for about £8. You can cut your charger lead and join the two wires to each side, or you can solder the same charge socket as what's on your battery to one side of the wattmeter and the same jack that's on your charger to the other side, so that you can connect it in or out when charging. It'll show voltage, charge current and amp-hours gone in to yoyr battery.
Why do you want to cut-off at 41v? You'll compromise the balancing if you don't fully charge it to 42v. I guess you've been reading theoretical stuff on ES. Some of this theory is for lithium batteties that were made years ago. Neatly all modern cells have ingredient X in them that combats all the shortcomings. Nobody knows what ingredient X is. They keep it a secret, but each brand has its own one.
Your battery is deigned to be charged to 42v and discharged to 31v. If it would be better to do it a different way, those values would be set in the charger and BMS. Take my advice: Use your battery like everybody else and it'll last a long time. By the time it's knackered, there will be much better ones anyway, so it'll give you a chance to improve something.
Charging your battery to 41v is a bit like in the old days when it cost extra for velour covered seats in your car. The people that paid extra for them wanted to keep them nice, so they put polythene or pvc covers on them.